High matrix interference affecting detection of PAH metabolites in bile of Atlantic hagfish (Myxine glutinosa) used for biomonitoring of deep-water oil production     

Sundt RC  Beyer J  Vingen S  Sydnes MO 《Marine environmental research》2011,71(5):369-374

The characteristic biology and wide distribution of hagfish species makes them relevant for use in pollution biomonitoring at great water depths, particularly in regions where deep-water oil production may take place. The exposure of fish to petrogenic contaminants can normally be detected from the level of polycyclic aromatic hydrocarbon (PAH) metabolites in bile fluid. Some of these metabolites are strong fluorophores, allowing analytical detection by means of simple fluorometric techniques such as fixed wavelength fluorescence (FF) and synchronous fluorescence scanning (SFS). In the present study bile from Atlantic hagfish (Myxine glutinosa) collected in pristine areas (Barents Sea and southwestern Norway) displayed strong bile fluorescence levels, suggesting the presence of PAH contaminants. However, gas-chromatography-mass spectrometry (GC-MS) analyses ruled out PAHs as the origin for this fluorescence signal. Rather, the bile of Myxine contains components resulting in unusually strong background fluorescence interfering at the wavelength pairs used for detection of PAH metabolites. Possible background for the observed matrix interference and implications for detection of PAH metabolites in hagfish is discussed.  相似文献   

Modelling thermal transients from magmatic underplating—an example from the Vøring margin (NE Atlantic)     

Magnus Wangen  Rolf Mjelde  Jan Inge Faleide 《Computational Geosciences》2011,15(4):771-788

The thermal impact of several kilometre-thick magmatic underplating in the lower continental crust is studied with analytical and numerical methods. Simple analytical solutions are derived for the thermal transient in the case of an infinite depth below the underplate and also for the case of a finite depth (down to the asthenosphere). It is shown that these solutions lead to simple approximations for when the transient surface heat flow is at its maximum, what the maximum is, and for how long the transient lasts. Even though these solutions assume that the underplate is emplaced instantaneously, they are useful in the interpretation of underplating over finite time spans. A numerical scheme is suggested for the modelling of underplating that handles both short time intervals as well as long intervals. The scheme treats magmatic underplating in a mass and energy conservative manner, and it is compared against the analytical solutions. Finally, the analytical and numerical results for thermal transients are applied to a transect from the Vøring margin (NE Atlantic), with respect to various degrees of early Cenozoic magmatic intrusion. It appears that more than half of the lower crustal body (LCB) in the Vøring margin must be magmatic underplating for the vitrinite reflectance to be substantially higher than for the non-magmatic case, where the LCB is assumed to comprise Caledonian crust.  相似文献   

Protoliths and phase petrology of whiteschists     

Leander Franz  Rolf L. Romer  Christian de Capitani 《Contributions to Mineralogy and Petrology》2013,166(1):255-274

Whiteschists appear in numerous high- and ultrahigh-pressure rock suites and are characterized by the mineral assemblage kyanite + talc (+-quartz or coesite). We demonstrate that whiteschist mineral assemblages are well stable up to pressures of more than 4 GPa but may already form at pressures of 0.5 GPa. The formation of whiteschists largely depends on the composition of the protolith, which requires elevated contents of Al and Mg as well as low Fe, Ca, and Na contents, as otherwise chloritoid, amphibole, feldspar, or omphacite are formed instead of kyanite or talc. Furthermore, the stability field of the whiteschist mineral assemblage strongly depends on XCO₂ and fO₂: already at low values of XCO₂, CO₂ binds Mg to carbonates strongly reducing the whiteschist stability field, whereas high fO₂ enlarges the stability field and stabilizes yoderite. Thus, the scarcity of whiteschist is not necessarily due to unusual P–T conditions, but to the restricted range of suitable protolith compositions and the spatial distribution of these protoliths: (1) continental sedimentary rocks and (2) hydrothermally and metasomatically altered felsic to mafic rocks. The continental sedimentary rocks that may produce whiteschist mineral assemblages typically have been deposited under arid climatic conditions in closed evaporitic basins and may be restricted to relatively low latitudes. These rocks often contain large amounts of the clay minerals palygorskite and sepiolite. Marine sediments generally do not yield whiteschist mineral assemblages as marine shales commonly have too high iron contents. Sabkha deposits may have too high CO₂ contents. Protoliths of appropriate geochemical composition occur in and on continental crust. Therefore, whiteschist assemblages typically are only found in settings of continental collision or where continental fragments were involved in subduction. Our calculations demonstrate that whiteschists can form by closed-system metamorphism, which implies that the chemical and isotopic composition of these rocks provide constraints on the development of the protoliths.  相似文献   

Indicators of road network vulnerability to storm-felled trees   总被引：1，自引：0，他引：1  

Rolf Nyberg  Magnus Johansson 《Natural Hazards》2013,69(1):185-199

In this paper, we exemplify the use of simple indicators of wind storm vulnerability of the road network that can be derived from existing geographic datasets. We point out the possible utilization of the datasets, applying GIS techniques, for highlighting road sections that, due to adjacency of high forest stands, are sensitive to closure by storm-felled trees. Indicators reflecting the reduced access to different areas or to the population in need of emergency aid can be derived based on the parameter tree height along roads and road network analysis. As a case in this study, the methodology is applied to elderly people (+80 years) with possible need of daily care at home following a severe storm. A comparison to the extreme 2005 storm felling in southern Sweden reveals that only limited estimates of road network disruption due to storm-felled trees are possible using the indicators, as other factors, for example, wind direction, which determine the exact impact of a particular storm are not taken into account. However, the indicators and network analysis also provide a possibility to draw attention to locations where disruptions of the road network would have significant effects on the accessibility to large surrounding areas. Potential critical road closures can be identified and preventive measures considered locally at these points.  相似文献   

Experimental investigation into the influence of stratification on the passive earth pressure     

Christian Gutberlet  Rolf Katzenbach  Kolumban Hutter 《Acta Geotechnica》2013,8(5):497-507

In this paper, the effect of inhomogeneous soil condition on the passive earth pressure is studied by using model tests. The model tests are carried out with two soil layers. The tests are compared with the corresponding results for homogenous soil. The shear band formation is identified with Particle Image Velocimetry measurements.  相似文献   

Crustal transect from the North Atlantic Knipovich Ridge to the Svalbard Margin west of Hornsund   总被引：1，自引：0，他引：1  

Frode Ljones  Asako Kuwano  Rolf Mjelde  Asbjrn Breivik  Hideki Shimamura  Yoshio Murai  Yuichi Nishimura 《Tectonophysics》2004,378(1-2):17-41

The crustal structure along a 312 km transect, stretching from the axial mountains of the North Atlantic Knipovich Ridge to the continental shelf of Svalbard, has been obtained using seismic reflection data and wide angle OBS data. The resulting seismic V_p and V_s models are further constrained by a 2-D-gravity model. The principal objective of this study is to describe and resolve the physical and compositional properties of the crust in order to understand the processes and creation of oceanic crust in this extremely slow-spreading counterpart of the North Atlantic Ridge Systems. V_p is estimated to be 3.50–6.05 km/s for the upper oceanic crust (oceanic layer 2), with a marked increase away from the ridge. The measured V_p of 6.55–6.95 km/s for oceanic layer 3A and 7.10–7.25 km/s for layer 3B, both with a V_p/V_s ratio of 1.81, except for slightly higher values at the ridge axis, does not allow a clear distinction between gabbro and mantle-derived peridotite (10–40% serpentized). The thickness of the oceanic crust varies a lot along the transect from the minimum of 5.6 km to a maximum of 8.1 km. The mean thickness of 6.7 km for the oceanic crust is well above the average thickness for slow-spreading ridges (<10 mm/year half-spreading rate). The areas of increased thickness could be explained by large magma production-rates found in the zones of axial highs at the ridge axis, which also have generated the off-axial highs adjacent the ridge. We suggest that these axial and off-axial highs along the ridge control the lithological composition of the oceanic crust. This approach suggests normal gabbroic oceanic crust to be found in the areas bound by the active magma segments (the axial and off-axial highs) and mantle-derived peridotite outside these zone.  相似文献   

Uptake and tissue distribution of C4-C7 alkylphenols in Atlantic cod (Gadus morhua): relevance for biomonitoring of produced water discharges from oil production     

Sundt RC  Baussant T  Beyer J 《Marine pollution bulletin》2009,58(1):72-79

The sensitivity of different tissues for assessment of chronic low-dose environmental exposure of fish to alkylphenols (APs) was investigated. We exposed Atlantic cod (Gadus morhua) in the laboratory to tritium labelled 4-tert-butylphenol, 4n-pentylphenol, 4n-hexylphenol, and 4n-heptylphenol via seawater (8 ng/l) and via contaminated feed (5 μg/kg fish per day). Measurements of different fish tissues during eight days of exposure and eight subsequent days of recovery revealed that APs administered via spiked seawater were readily taken up whereas the uptake was far less efficient when APs were administered in spiked feed. AP residues were mainly located in the bile fluid whereas the concentrations in liver were very low, indicating a rapid excretion and the liver-bile axis to be the major route of elimination. The biological half-life of APs in the exposed cod was short, between 10 and 20 h. Our study shows that in connection with biomonitoring of AP exposure in fish, assessment of AP metabolites in bile fluid is a more sensitive tool than detection of parent AP levels in liver or other internal tissues.  相似文献   

A land surface data assimilation framework using the land information system: Description and applications     

Sujay V. Kumar  Rolf H. Reichle  Christa D. Peters-Lidard  Randal D. Koster  Xiwu Zhan  Wade T. Crow  John B. Eylander  Paul R. Houser 《Advances in water resources》2008

The Land Information System (LIS) is an established land surface modeling framework that integrates various community land surface models, ground measurements, satellite-based observations, high performance computing and data management tools. The use of advanced software engineering principles in LIS allows interoperability of individual system components and thus enables assessment and prediction of hydrologic conditions at various spatial and temporal scales. In this work, we describe a sequential data assimilation extension of LIS that incorporates multiple observational sources, land surface models and assimilation algorithms. These capabilities are demonstrated here in a suite of experiments that use the ensemble Kalman filter (EnKF) and assimilation through direct insertion. In a soil moisture experiment, we discuss the impact of differences in modeling approaches on assimilation performance. Provided careful choice of model error parameters, we find that two entirely different hydrological modeling approaches offer comparable assimilation results. In a snow assimilation experiment, we investigate the relative merits of assimilating different types of observations (snow cover area and snow water equivalent). The experiments show that data assimilation enhancements in LIS are uniquely suited to compare the assimilation of various data types into different land surface models within a single framework. The high performance infrastructure provides adequate support for efficient data assimilation integrations of high computational granularity.  相似文献   

Elimination of Carbamazepine,Diclofenac and Naproxen from Treated Wastewater by Nanofiltration     

Markus Röhricht  Jürgen Krisam  Ulrich Weise  Uta R. Kraus  Rolf‐A. Düring 《洁净——土壤、空气、水》2009,37(8):638-641

Most conventional wastewater treatment plants remove very small amounts of micropollutants, such as pharmaceuticals. Here, the ability of two different types of submerged nanofiltration flat sheet modules to remove pharmaceuticals from wastewater is analyzed. The two nanofiltration membranes were used at relatively low pressures of only 0.3 and 0.7 bar. At such low pressures, the membranes did not retain salts to a great extent. This is advantageous in wastewater treatment because no salt concentrate is produced. Carbamazepine was retained only slightly by the nanofiltration membranes, whereas approximately 60% of diclofenac and naproxen were retained by both membranes. This level of effectiveness might not be enough to justify the use of such a system as an additional treatment step in wastewater treatment plants.  相似文献   

Active Galactic Nuclei     

Martin Haas  Peter Biermann  Rolf Chini  Jochen Heidt  Wolfram Kollatschny  Helmut Meusinger  Ralf Siebenmorgen 《Astronomische Nachrichten》2007,328(7):665-680

F11 Jets, supernovae, gammabursts – more light for theory? F35 A Direct Comparison of the QSO Samples from VPMS and SDSS F36 Gravitational Microlensing Simulations and Ensemble Broad‐Band Variability of the QSOs from VPMS F42 Luminosity function of low redshift quasars F43 Star Formation around Active Galactic Nuclei – Results from near infrared observations F58 High‐Redshift Quasars as Probes of Early Star Formation F66 On the dust emission of Seyfert nuclei F72 Propagation of Very Light MHD Jets F78 Giant Outflows in MassiveHigh‐z Radio Galaxies: Direct Evidence for AGNFeedback in the Early Universe F89 Lowfrequency mapping of ‘normal’ FR II radio galaxies: Resolving the puzzle of X‐shaped radio sources F90 Nature of X‐shaped radio sources: A statistical approach F100 Cosmological growth of Supermassive Black Holes: constraints on kinetic and radiative energy feedback F107 Molecular Tori in AGN F136 Electron‐Ion Recombination Rate Coefficients of Iron M‐Shell Ions for X‐Ray Astronomy F139 Hydrodynamic models of obscuring tori F145 The unique BL Lac Object S5 0716+714 F158 On the Cluster Environment of the BL Lac Object OJ 287 F179 The circumnuclear dust in nearby AGN resolved by mid‐infrared interferometry F184 NIR‐imaging of SDSS BL Lac objects F190 Blazar Observations in the TeV energy range with the MAGIC Telescope F198 Gas Inflow Rates in Nearby AGN Galaxies F202 Two zone SSC model for blazar jets F215 Long‐termVHE γ ‐ray monitoring of bright blazars with a dedicated telescope F218 Long termmonitoring of bright TeV Blazars with the MAGIC telescope F220 Fifteen Blazars in Very‐High Energy Gamma Rays: A Comparative Study F229 Numerical calculation of blazar spectra. Application to 1 ES 1218+30.4 F230 Blazar spectral energy distributions corrected for gamma ray attenuation F240 Observation of PG 1553+113 with the MAGIC Telescope F243 VHE Gamma‐Ray Flare of PKS2155‐304 detected by the MAGIC telescope F245 Observations of 3C279 with the MAGIC Telescope F258 Diffraction limited near infrared imaging spectroscopy of the NLR of NGC4151  相似文献